Tuesday, May 30, 2017

The Ghent Altarpiece: A Chemical investigation



The Ghent Altarpiece is a  huge painting that adorns the altar of St Bavo's cathedral, Ghent, Belgium. Measuring 11ft x14ft overall,  it consists of 12 foldable oak panels depicting  biblical themes.  Conceived and created by  van Eyck brothers Jan and Hubert  the work was completed in 1432.  The lower middle  panel " Adoration of the Mystic Lamb" unifies the entire work.

Renaissance artists like van Eyck brothers  the mostly used  mineral  pigments.  For example  goethite  a mixture of iron oxide-hydroxide with a sprinkle of manganese went by the name brown ochre or brown earth. Green earth was glauconite/celadonite a complex  mixed silicate of aluminium, iron, potassium and magnesium. Red ochre was hematite dehydrated iron oxide.  Yellow ochre, which is hydrated iron oxide could yield bright yellow to  orange.  For deep orange artists used orpiment,  arsenic sulphide. Ultra marine blue was the costliest colour  obtained by grinding  lapis lazuli and extracting the powder with water. Azurite was also used for blue. And for black either carbon black from soot or  peach stones charred and ground to a fine powder were used. Working with oil paints   artists might have instinctively and intuitively discovered the extra dimension glaze added to the painting. 
Ghent Altarpiece: Panels open (courtesy: wiki


The Ghent altarpiece  has aged through rough times. Hence it  is possible that it might  have undergone
Ghent Altarpiece: Panels closed (courtesy wiki)
several cycles of   restore/reconstruct/repair.   How to get down to the innermost layer of paint laid down originally by van  Eyck brothers almost six hundred years ago?  University of Antwerp, Royal institute for Cultural heritage, Brussels and the University of Ghent  brought their scientists together and thus began a project on  the detailed analysis of the The Ghent Altarpiece.  A recent issue of Angewandte  Chemie International edition(1) carries their probe analysis.  
Dr van der Snickt, corresponding author of the paper is  with  the dept. of chemistry,  University of Antewerp, and his research area   is conservation and restoration of heritage art. Dr Snickt uses modern analytical tools which are non-invasive such as  Macroscopic X-ray fluorescence(MA-XRF), secondary electron microscopy- energy dispersive X-ray analysis(SEM-EDX), and synchrotron radiation based micro-XRF(SR-- muXRF).   These are basically chemical imaging techniques and specific to each element. In other words elements yield  their  characteristic signature pattern.   Hand-held scanning devices were used to image the entire surface. 16 billion spectra were thus collected, processed and analysed.  They also analysed the cross section of a tiny speck of paint layer by layer.   They discovered the yellow varnish layers underneath  large areas which have been overpainted. They also observed that damaged spots in the original painting have been filled out with iron containing putty like material and then painted over. Since  advent of organic dyes in 18th century pushed  out mineral colours, the team could also  get a rough idea when repair/restoration were carried out.


Tailpiece: 
The lower left panel depicting the Righteous Judges has been missing for decades. A copy created by Jef Van der Veken stands in its place.  In Albert Camus' novel The fall,  Clamence boasts that the original  is in his possession. He won't return it  because none  misses the original all are happy with the copy also because innocent lambs and righteous judges no longer exist in modern times.     

REFERENCES:

1. Large-Area Elemental Imaging Reveals Van Eyck's Original Paint Layers on the Ghent   
     Altarpiece (1432), Rescoping Its Conservation Treatment
     Geert Van der Snickt et al,  Angewandte Chemie International Edition
     Volume 56,  Issue 17pages 4797–4801April 18, 2017